Publications

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Susannah L. Scott, Anqiu Fu, and Leonard A. MacAdams “Effect of silica type and grafting method on the reactivity of tetraneopentylchromium(IV) towards and on silica” Inorganica Chimica Acta . 2008, Article in Press

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Katharine Page, Jun Li, Robert Savinelli, Holly N. Szumila, Jinping Zhang, Judith K. Stalick, Thomas Proffene, Susannah L. Scott, and Ram Seshadri “Reciprocal space and real-space neutron investigation of nanostructured Mo2C and WC” Solid State Sci. 2008, Article in Press

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Cori A. Demmelmaier, Rosemary E. White, Jeroen A. van Bokhoven, and Susannah L. Scott “Nature of ≡SiOCrO2Cl and (≡SiO)2CrO2 Sites Prepared by Grafting CrO2Cl2 onto Silica” J. Phys. Chem. C. 2008, Article in Press

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Miyako Hisamoto and Susannah L. Scott “IR Spectroscopic Investigation of cis-(CH3)2Au(O,O'-acac) and cis-(CD3)2Au(O,O'-acac)” Spectrochim. Acta, Part A. 2008, Article in Press

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Ritu Ahuja, Sabuj Kundu, Alan S. Goldman, Maurice Brookhart, Brian C. Vicente, and Susannah L. Scott “Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes” ChemComm. 2008, pp. 253-255.

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Susannah L. Scott “Catalytic Transformations of Seed Oil Derivatives via Olefin Metathesis ” Helia. 2007, 30(46), pp. 133-142.

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Anthony W. Moses, Christina Raab, Ryan C. Nelson, Heather D. Leifeste, Naseem A. Ramsahye, Swarup Chattopadhyay, Juergen Eckert, Bradley F. Chmelka, and Susannah L. Scott “Spectroscopically Distinct Sites Present in Methyltrioxorhenium Grafted onto Silica-Alumina, and their Abilities to Initiate Olefin Metathesis” J. Am. Chem. Soc. 2007, 129, pp. 8912-8920.

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Udayshankar G. Singh, Jun Li, Joseph W. Bennett, Andrew M. Rappe, Ram Seshadri, and Susannah L. Scott, “A Pd-doped Perovskite Catalyst, BaCe1-xPdxO3-d, for CO Oxidation” Journal of Catalysis. 2007, 249, pp. 349-358.

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Jun Li, Udayshankar G. Singh, Joseph W. Bennett, Katharine Page, James Weaver, Jinping Zhang, Thomas Proffen, Andrew M. Rappe, Susannah L. Scott, and Ram Seshadri,, “BaCe 1-x Pd x O 3± d (0 < x < 0.1): Redox controlled ingress and egress of palladium in a perovskite” Chem. Mater. 2007, 19(6), pp. 1418-1426.

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Anthony W. Moses, Heather D. Leifeste, Naseem Ramsahye, Juergen Eckert, and Susannah L. Scott, "Supported Re catalysts for the Metathesis of functionalized olefins” Catal. Org. React. 2007, 115, pp. 13-22.

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Fuad A. Ababneh, Susannah L. Scott, Hassan A. Al-Reasi, and David R. S. Lean, "Photochemical reduction and reoxidation of aqueous mercuric chloride in the presence of ferrioxalate and air". Sci. Tot. Environ. 2006, 367(2-3) 831-839.

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Anthony W. Moses, Naseem A. Ramsahye, Christina Raab, Heather D. Leifeste, Swarup Chattopadhyay, Brad F. Chmelka, Juergen Eckert, and Susannah L. Scott, "Methyltrioxorhenium Interactions with Lewis Acid Sites of an Amorphous Silica-Alumina". Organometallics. 2006, 25(9) 2157-2165.

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Ziyad A. Taha, Eric W. Deguns, Swarup Chattopadhyay, and Susannah L. Scott, "Formation of Digallium Sites in the Reaction of Trimethylgallium with Silica" Organometallics. 2006, 25(8), 1891-1899.

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Valbona Celo, David R. S. Lean, and Susannah L. Scott "Abiotic methylation of mercury in the aquatic environment", Sci. Tot. Environ. 2006, 368(1) 126-137.


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Nazafarin Lahoutifard, Laurier Poisssant, and Susannah L. Scott, "Scavenging of gaseous mercury by acidic snow at Kuujjuarapik, Northern Quebec" Sci. Tot. Environ. 2006, 355(1-3), 118-126.


link Susannah L. Scott, Tamara L. Church, Dao Hinh Nguyen, Elizabeth A. Mader, and Joseph Moran,  "An investigation of catalyst/cocatalyst/support interactions in silica-supported olefin polymerization catalysts based on Cp*TiMe3*" Top. Catal.  200534, 109-120.


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George D. Meitzner, Jorge L. Gardea-Torresdey, Jason G. Parsons, Susannah L. Scott, and Eric W. Deguns, "The Effect of Cryogenic Sample Cooling on X-ray Absorption Spectra", Microchem. J. 2005, 81, 61-68.


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Valbona Celo, and Susannah L. Scott, "Kinetics and Mechanism of the Mercury(II)-Assisted Hydrolysis of Methyl Iodide" Inorg. Chem. 2005, 44, 2507-2512.


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Eric W. Deguns, Ziyad Taha, George D. Meitzner, and Susannah L. Scott. "An X-ray Absorption Study of Two VOCl3-modified Silicas: Evidence for Chloride-Silica Interactions" J. Phys. Chem. B  2005, 109, 5005-5011.


link Nazafarin Lahoutifard, and Susannah L. Scott  "Reply to "Comment on 'Kinetics and Mechanism of Nitrite Oxidation by HOBr/BrO- in Atmospheric Water and Comparison with Oxidation by HOCI/CIO-' "" J. Phys. Chem. A. 2004, 108, 10617-10618.


 link Mohamed Siaj, Corey Reed, S. Ted Oyama, Susannah L. Scott, and Peter H. McBreen, "Dissociation of Acetaldehyde and Beta-Mo2C to Yield Ethylidene and Oxo Surface Groups: A Possible Pathway for Active Site Formation in Heterogeneous Olefin Metathesis", J. Am. Chem. Soc.  2004, 126, 9514-9515.
   
pdf Susannah L. Scott, and Azfar Hassan, "Preparation and Activity of a V-Ti/Silica Catalyst for Olefin Epoxidation", Chemical Industries, (Dekker), 90 , 2004, Catal. Org. React.
   
link Valbona Celo, Ram .V. Ananth, Susannah L. Scott, and David R.S. Lean, "Methylmercury Artifact Formation During Solid-Phase Extraction of Water Samples Using Sulfhydryl Cotton Fiber Adsorbent" Anal. Chem. Acta, 2004, 516, 171-177.
   
pdf Valbona Celo, Susannah L. Scott, and David R.S. Lean  "Rates and Mechanisms of Mercury Methylation by Methyltin Compounds in the Aquatic Environment" RMZ-Materials and Geoenvironment, 2004, 51, 919-922
   
pdf Valbona Celo, Susannah L. Scott, and David R.S. Lean, "Abiotic Methylation of Mercury in the Aquatic Environment" RMZ-Materials and Geoenvironment, 2004, 51, 915-918
   
link Soumen Sensarma, Abdillahi Omar Bouh, Susannah L. Scott, and Howard Alper "Olefin epoxidation catalyzed by an air stable-supported titanium catalyst" J. Mol. Catal. A: Chem. 2004, 203, 145-152.
   
 link Susannah L. Scott, Allison Mills, Chhor. Chao, Jean-Marie Basset, Nicolas Millot, and Catherine C. Santini "Silica-supported Rhodium Hydrides Stabilized by Triisopropylphosphine" J. Mol. Catal. A: Chem.  2003, 204-205, 457-463.
   
 link Susannah L. Scott, Huda Yusuf, Nazafarin Lahoutifard, and Kristie Maunder "Homogeneous and Heterogeneous Reactions of Atmospheric Mercury (II) and Sulfur (IV)", J. Phys. IV 2003, 107, 1201-1204.
   
 link Nazafarin Lahoutifard, Laurier Poissant, and Susannah L. Scott  "Heterogeneous Scavenging of Atmospheric Mercury by Snow Spiked with Hydrogen Peroxide" J. Phys. IV 2003, 107, 711-714.



Susannah L. Scott and Eric W. Deguns, Multifunctional Active Sites on Silica Surfaces by Grafting of Metal Complexes, in "Nanostructured Catalysts", S. L. Scott, C. M. Crudden and C. W. Jones, Eds, Kluwer/Plenum: New York, 2003, pp. 1-14.


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Susannah L. Scott, Cathleen M. Crudden, and Christopher W. Jones, Eds, "Nanostructured Catalysts" in Nanostructure Science and Technology, Vol 3, Kluwer Academic/Plenum Publishers: New York, 2003.


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Abdillahi O. Bouh, Azfar Hassan and Susannah L. Scott, Stoichiometry and Kinetics of Gas Phase Cyclohexene Epoxidation by a Silica-supported tert-Butylperoxodititanium Complex, in Catalysis of Organic Reactions, Ed. D. Morrell, Chemical Industries, 2003, 89, Marcel Dekker: New York, 537-543.


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Nazafarin Lahoutifard, Philippe Lagrange, Janine Lagrange and Susannah L. Scott, "Kinetics and Mechanism of Nitrite Oxidation by HOBr/BrO- in Atmospheric Water and Comparison with Oxidation by HOCl/ClO-"J. Phys. Chem. A. 2002, 106, 11891-11896.


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Tagenine Alladin, Marcel C. Beaudoin, and Susannah L. Scott, "Neopentylidene Complexes of Ti and Zr Obtained by Thermolysis of Silica-supported Bis(neopentyl) Complexes" Inorg. Chem. Acta. 2002, 345, 292-298


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Matthew K. Richmond, Howard Alper, Susannah L. Scott, and Glenn P. A. Yap, "Preparation of Dinuclear Phosphine-bridged Palladium(II) Species and their Silica-bound Analogues as Catalysts for the Cyclization of Aminoalkynes" Organometallics.2002, 21, 3395-3400. 


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Marcel. C. Beaudoin, Omisola Womiloju, Anqiu Fu, Jamila Amor Nait Ajjou, Gordon L. Rice, and Susannah L. Scott, "Silica-supported Alkylidene Complexes:  Their Preparation, Characterization and Reactivity, Especially towards Olefins" J. Mol. Catal. A: Chem. 2002, 190, 159-169.


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Matthew K. Richmond, Susannah L. Scott, and Howard Alper, "Preparation of New Catalysts by the Immobilization of Palladium(II) Species onto Silica:  An Investigation of Their Catalytic Activity for the Cyclization of Aminoalkynes" J. Am. Chem. Soc. 2001, 123, 10521-10525. 


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Lisa Van Loon, Elizabeth Mader, and Susannah L. Scott, "Sulfite Stabilization and Reduction of the Aqueous Mercuric Ion:  Kinetic Determination of Sequential Formation Constants" J. Phys. Chem. A 2001, 105, 3190-3195.


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Susannah L. Scott, and Jamila Amor Nait Ajjou, "Surface Organometallic Investigation of the Mechanism of Ethylene Polymerization by Silica-supported Cr Catalysts" Chem. Eng. Sci. 2001, 56, 4155-4168.


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Marcel Beaudoin and Susannah L. Scott "Spontaneous Evolution of Silica-supported Ti Amide Fragments to Imine and Imido Complexes" Organometallics.2001, 20, 237-239.


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Fengfu Li, Glenn P. A. Yap, Susannah L. Scott, and Seong Ihl Woo, "Reaction of NiBr2(DME) with 2-pyridinal-methyl-N-2,6-diisopropylphenylimine. The First Crystal Structure of an alpha-Diimine Nickel(II) Complex of the NiL2X2 Type" Trans. Met. Chem. 2001, 26, 271-275.


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Jamila Amor Nait Ajjou and Susannah L. Scott, "A Kinetic Study of Ethylene and 1-Hexene Homo- and Copolymerization Catalyzed by a Silica-Supported Cr(IV) Complex: Evidence for Propagation by a Migratory Insertion Mechanism" J. Am. Chem. Soc. 2000, 122, 8968-8976.


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Carmen Roveda, Tamara L. Church, Howard Alper, and Susannah L. Scott, "Modification of Silica Surfaces by Metallasiloxanes Containing Mo and Ti:  Evidence for Concurrent Metal and Ligand Chemisorption" Chem. Mater. 2000, 12, 857-862. 


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Lisa Van Loon, Elizabeth Mader, and Susannah L. Scott, "Reduction of the Aqueous Mercuric Ion by Sulfite:  UV Spectrum of HgSO3 and its Intramolecular Redox Reaction" J. Phys. Chem. A. 2000, 104, 1621-1626.


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Abdillahi Omar Bouh, Gordon L. Rice, and Susannah L. Scott, "Mono- and Dinuclear Silica-supported Titanium(IV) Complexes and the Effect of TiOTi Connectivity on Reactivity" J. Am. Chem. Soc. 1999, 121, 7201-7210.


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Jamila Amor Nait Ajjou, Gordon L. Rice, and Susannah L. Scott, "Kinetics and Mechanisms of Thermally Induced Alkane Eliminations from Silica-supported Bis(alkyl)chromium(IV) and -vanadium(IV) Complexes" J. Am. Chem. Soc. 1999, 120, 13436-13443.  


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Susannah L. Scott, Mikolaj Szpakowicz, Allison Mills, and Catherine C. Santini, "Ligand Exchange and Oxidative Addition on a Silica-supported Rhodium Complex, trans-[(SiO)Rh(PMe3)2(CO)]"  J. Am. Chem. Soc. 1998, 120, 1883-1890. 


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Jamila Amor Nait Ajjou, Susannah L. Scott, and Valarie Paquet, "Synthesis and Characterization of Silica-stabilized Chromium(IV) Alkylidene Complexes",J. Am. Chem. Soc. 1998, 120, 415-416.


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Gordon L. Rice and Susannah L. Scott,  "Non-hydrolytic Surface Synthesis of a Heterobimetallic V-Ti Alkoxide Complex on Silica" Chem. Mater. 1998, 10, 620-625.


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Gordon L. Rice and Susannah L. Scott, "Site-specific oxygen-18 labelling of silica-supported vanadium(V) complexes: Implications for oxidation catalysis"  J. Mol. Catal. A: Chem. 1997, 125, 73-79.


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Jamila Nait Ajjou and Susannah L. Scott, "Reactions of Tetraalkylchromium(IV) with Silica:  Mechanism of Grafting and Characterization of Surface Organometallic Complexes" Organometallics. 1997, 16, 86-92.


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Gordon L. Rice and Susannah L. Scott, "Characterization of Silica-supported Vanadium(V) Complexes Derived from Molecular Precursors and Their Ligand Exchange Reactions" Langmuir1997, 13, 1545-1551. 


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Catherine C. Santini, Susannah L. Scott, and Jean-Marie Basset, "Supramolecular Approach to Metal-Support Interactions:  Reactivity of Silica-Supported Bis(allyl)rhodium(III) and the Influence of Surface Hydroxyl Groups" J. Mol. Catal A: Chem. 1996, 107, 263-271.


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Susannah L. Scott, Pascal Dufour, Catherine C. Santini, and Jean-Marie Basset,  "Surface Organometallic Chemistry on Oxides:  Reaction of Trimethylphosphine with Bis(allyl)rhodium Grafted onto Silica" Inorg. Chem. 1996, 35, 869-875.


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A. D. Jordan, Susannah L. Scott, and Robert B. Jordan, "Kinetics of the Reaction of Chromium(II) with Ethyliodoacetate and Iodoacetatopentaamminecobalt(III)" Inorg. Chim. Acta. 1995, 239, 99-106.


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Susannah L. Scott, Craig Crippen, Catherine C. Santini, and Jean-Marie Basset, "Supramolecular Approach to Metal-Support Interactions:  Formation and Decarbonylation of Allyl Alcohol by an Oxide-Supported (sigma-allyl)rhodium(III) Complex", J. Chem. Soc., Chem. Commun. 1995, 1875-1876.


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Andreja Bakac, Susannah L. Scott, James H. Espenson, and Kenton R. Rodgers, "Interaction of Chromium(II) Complexes with Molecular Oxygen:  Spectroscopic and Kinetic Evidence for eta1- Superoxo Complex Formation"  J. Am. Chem. Soc.1995, 117, 6483-6488.



Susannah L. Scott, Jean-Marie Basset, Gerald P. Niccolai, Catherine C. Santini, Jean-Pierre Candy, Christine Lecuyer, Francoise Quignard, and Agnes Choplin, "Surface Organometallic Chemistry: A Molecular Approach to Heterogeneous Catalysis" New J. Chem. 1994, 18, 115-122.


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Susannah L. Scott and Jean-Marie Basset, "Coordination Chemistry on Surfaces:  A New Method to Graft Rhenium(VII) Oxide on Highly Dehydroxylated Oxides" J. Am. Chem. Soc. 1994, 116, 12069-12070.


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Pascal Dufour, Susannah L. Scott, Catherine C. Santini, Frederic Lefebvre, and Jean-Marie Basset, "Surface Organometallic Chemistry on Oxides:  Reaction of Carbon Monoxide with Bis(allyl)rhodium Grafted onto Silica, Titania and Alumina" Inorg. Chem. 1994, 33, 2509-2517.


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Susannah L. Scott, Pascal Dufour, Catherine C. Santini, and Jean-Marie Basset, "Surface-mediated organometallic synthesis of [=SiO] – [RhH 2 (PMe 3 ) 4 ] + : the first example of a cationic organometallic complex attached to the silica surface by ion pairing" J. Chem. Soc. Chem. Commun. 1994, 2011-2012


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Susannah L. Scott and Jean-Marie Basset, "Stoichiometric and Catalytic Reactivity of Organometallic Fragments Supported on Inorganic Oxides" J. Mol. Catal. 1994, 86, 5-22.



Jean-Marie Basset, Susannah. L. Scott, Agnes. Choplin, Matthew Leconte, Francois Quignard, Catherine Santini, and Andre Theolier, Organometallic Chemistry as a Basis for Understanding Heterogeneous Catalysis, in Proceedings of the NATO Advanced Workshop on Elementary Reaction Steps in Heterogeneous Catalysis,1993 Kluwer: Dordrecht,pp. 39-49.


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Susannah L. Scott, James H. Espenson, and Wen-Jang Chen, "Electron Transfer Reactions of 17-electron and 19-electron Organometallic Radicals, CpW(CO)3 and CpW(CO)3PPh3" Organometallics. 1993, 12, 4077-4084.


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Susannah L. Scott, Wen Jang Chen, Andreja Bakac, and James H. Espenson, "Spectroscopic parameters, electrode potentials, acid ionization constants, and electron exchange rates of the 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) radicals and ions" J. Phys. Chem. 1993, 97, 6710-6714.


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Susannah L. Scott, James H. Espenson, and Andreja Bakac, "Photochemical Generation of [Rh(dmgH)2PPh3]2 from [CpW(CO)3]2 and XRh(dmgH)2PPh3 (X is Cl, Br) with Intermediate 17-Electron Tungsten and Rhodium Radicals" Organometallics.1993, 12, 1044-1047.


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Susannah L. Scott, James H. Espenson, and Zuolin Zhu,  "Reactivity of 17-electron Organometallic Tungsten and Molybdenum Radicals:  A Laser Flash Photolysis Study" J. Am. Chem. Soc. 1993, 115, 1789-1797.


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Susannah L. Scott, Andreja Bakac, and James H. Espenson, "Preparation and Reactivity of a Cationic Dichromium-Semiquinone Complex" J. Am. Chem. Soc. 1992, 114, 4605-4610.


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Susannah L. Scott, Andreja Bakac, and James H. Espenson, "Oxidation of Alcohols, Aldehydes and Carboxylic Acids by Aquachromium(IV)" J. Am. Chem. Soc. 1992, 114, 4205-4213.


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Susannah L. Scott, Andreja Bakac, and James H. Espenson, "Preparation and reactivity of the aquachromium(IV) ion" J.  Am. Chem. Soc. 1991, 113, 7787-7788.


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Susannah L. Scott, Andreja Bakac, and James H. Espenson, "Catalytic Oxidation of Hydroxymethylchromium(III) by  the Superoxochromium(III) Ion"  Inorg. Chem. 1991, 30, 4112-4117.


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Novelette Sadler, Susannah L. Scott, Andreja Bakac, James H. Espenson, and M. S. Ram, "Effect of Steric Crowding on the Rates of Reactions of a Nickel(I) Tetraaza Macrocycle with Organic Halides and Hydroperoxides [Erratum to document cited in CA111(18):161380z]" Inorg. Chem. 1990, 28, 3951-3954.


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Novelette Sadler, Susannah L. Scott, Andreja Bakac, James H. Espenson, and M. S. Ram, "Effect of Steric Crowding on the Rates of Reactions of a Nickel(I) Tetraaza Macrocycle with Organic Halides and Hydroperoxides" Inorg. Chem. 1989, 28, 3951-3954.


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Thomas Heinis, Swapan Chowdhury, Susannah L. Scott, and Paul Kebarle, "Electron Affinities of Substituted Benzo-, Naptho- and Anthraquinones Determined from Gas-Phase Equilibria Measurements"  J. Am. Chem. Soc. 1988, 110, 400-407.